Mate did you ever solve thisd? as having the exact same proble.
Solutions offered include:
Put them in lr-imame4all which uses the Retroarch configs HOWEVER there isn’t a map/hotkey via my PS3 set up for insert coin/start game (by default 5 and 1 on keyboard!)
SO then someone suggested setting upa hotkey.. BUT i am struggling to locate my PS3 USB mapping file. I saw Floobs video on it, well spoken and described BUT it was running on an old version and my set up / file positions seem totally different.
Sorry to not offer you a solution but anything I find or if you have a solution we sould share.